Effect of nanosized SiO

S. Suarez, S. Abbrent, S.G. Greenbaum, J.H. Shin, S. Passerini

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

An extensive NMR investigation of filler-free and SiO2nanoparticle-containing P(EO)20LiBETI polymer electrolytes prepared through a solvent-free procedure is reported.7Li and19F NMR spectra, spin-lattice relaxation times and self-diffusion coefficients were measured in the temperature range extending from 25 to 100 °C. There was essentially no difference in the DLifor filler-free and nanosized SiO2-containing P(EO)20LiBETI at T≥80 °C. The DFshowed differences at T≤90 °C, with the SiO2-containing P(EO)20LiBETI having the greater DF. Discrepancies between calculated and measured ionic conductivity are attributed to variable length scale diffusion within heterogeneous media, rather than ion pairing effects. © 2003 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)407 - 415
Number of pages9
JournalSolid State Ionics
Volume166
Issue number3-4
DOIs
Publication statusPublished - 30 Jan 2004
Externally publishedYes

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Suarez, S., Abbrent, S., Greenbaum, S. G., Shin, J. H., & Passerini, S. (2004). Effect of nanosized SiO. Solid State Ionics, 166(3-4), 407 - 415. https://doi.org/10.1016/j.ssi.2003.11.009