Ethanol steam reforming kinetics of a Pd-Ag membrane reactor

Silvano Tosti, Angelo Basile, Rodolfo Borelli, Fabio Borgognoni, Stefano Castelli, Massimiliano Fabbricino, Fausto Gallucci, Celeste Licusati

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The ethanol steam reforming reaction carried out in a Pd-based tubular membrane reactor has been modelled via a finite element code. The model considers the membrane tube divided into finite volume elements where the mass balances for both lumen and shell sides are carried out accordingly to the reaction and permeation kinetics. Especially, a simplified "power law" has been applied for the reaction kinetics: the comparison with experimental data obtained by using three different kinds of catalyst (Ru, Pt and Ni based) permitted defining the coefficients of the kinetics expression as well as to validate the model. Based on the Damkohler-Peclet analysis, the optimization of the membrane reformer has been also approached. © 2009 International Association for Hydrogen Energy.
Original languageEnglish
Pages (from-to)4747 - 4754
Number of pages8
JournalInternational Journal of Hydrogen Energy
Issue number11
Publication statusPublished - Jun 2009
Externally publishedYes


All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

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