Robust Mesoporous CoMo/γ-Al

Rudina Bleta, Benedetto Schiavo, Natale Corsaro, Paula Costa, Alberto Giaconia, Leonardo Interrante, Eric Monflier, Giuseppe Pipitone, Anne Ponchel, Salvatore Sau, Onofrio Scialdone, Sébastien Tilloy, Alessandro Galia

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4 Citations (Scopus)

Abstract

Hydrothermal liquefaction (HTL) is a promising technology for the production of biocrude oil from microalgae. Although this catalyst-free technology is efficient under high-temperature and high-pressure conditions, the biocrude yield and quality can be further improved by using heterogeneous catalysts. The design of robust catalysts that preserve their performance under hydrothermal conditions will be therefore very important in the development of biorefinery technologies. In this work, we describe two different synthetic routes (i.e., impregnation and cyclodextrin-assisted one-pot colloidal approach), for the preparation in aqueous phase of six high surface area CoMo/γ-Al2O3catalysts. Catalytic tests performed on the HTL of Nannochloropsis gaditana microalga indicate that solids prepared by the one-pot colloidal approach show higher hydrothermal stability and enhanced biocrude yield with respect to the catalyst-free test. The positive effect of the substitution of the block copolymer Tetronic T90R4 for Pluronic F127 in the preparation procedure was evidenced by diffuse reflectance UV-visible spectroscopy, X-ray diffraction, N2-adsorption-desorption, and H2-temperature-programmed reduction measurements and confirmed by the higher quality of the obtained biocrude, which exhibited lower oxygen content and higher-energy recovery equal to 62.5% of the initial biomass.
Original languageEnglish
Pages (from-to)12562 - 12569
Number of pages8
JournalACS Applied Materials and Interfaces
Volume10
Issue number15
DOIs
Publication statusPublished - 18 Apr 2018
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Bleta, R., Schiavo, B., Corsaro, N., Costa, P., Giaconia, A., Interrante, L., Monflier, E., Pipitone, G., Ponchel, A., Sau, S., Scialdone, O., Tilloy, S., & Galia, A. (2018). Robust Mesoporous CoMo/γ-Al. ACS Applied Materials and Interfaces, 10(15), 12562 - 12569. https://doi.org/10.1021/acsami.7b16185